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SYNTHESIS OF TiN BY MICROWAVE CARBOTHERMAL REDUCTION OF TiO_2

B.H Liu , Y Zhang , S.X. Ouyang , and H.C. Gu (Research Institute of Technical Chemical Physics , East China University of Science and Technology , Shanghai 200237 , China)(Department of Materials Physics , University of Science and Technology Beijing , Beijing 100083 , China)(State Key Laboratory for Synthesis and Processing of Advanced Materials , Wuhan University of Technology , Wuhan 430070 , China)

金属学报(英文版)

Titanium nitride powder was synthesized by microwave carbothermal reduction of titanium oxide. The mechanism and thermal dynamics of the reaction process were studied. The results show that the microwave carbothermal reduction technology has unique advantages over the conventional reduction methods. It can not only lower the reaction temperature, shorten the synthesis cycle, but also refine the product particles,as well as improving the reactivity of the powder.

关键词: TiN microwave , null

NVESTIGATION OF PRODUCTOPN OF FUNCTIONALLY GRADIENT MATERIAL BY ELECTROLESS PLATING

Z.M.Xu1) , J.S.Zhen1) , H.F.Liu1) and L.M.Zhang2) 1)Departent of Chemistry , Huazhong University of Science and Technology , Wuhan 430074 , China 2)Institute of Materials Science and Engineering , Wuhan University of Technology , Wuhan 430070 , China

金属学报(英文版)

Thispaper proposed a new methodof producing Ceramic/ Metalfunctionally gradient mate rialby electroless platingtechnique. The experimentof producing SiC/ Ni PFGM wascar ried out with self made electroless plating facilities. The results show that the thickness of FGMcoating andthegradientdistribution ofcompositioncanbecontrolled byoptimizingelec trolessplating technology and changing the parameters such as plating time, the additionspeed and concentration of SiCparticles. Analysisdemonstratesthatthereisastrongrelation ship amongthe SiCcontent,the microstructureandthe mechanicalproperty ofthe FGM.

关键词: electrolessplating , null , null

Preparation and Gas-sensing Characteristics of Na~+-doped ZnO Single Crystals

Suying PAN and Junbiao MAO (Center for Materials Research and Analysis , Wuhan University of Technology , Wuhan , 430070 , China)(To whom correspondence should be addressed)

材料科学技术(英)

ZnO single crystals were grown by vapor phase reaction of Zno powder with active carbon powdei at an elevated temperature The typical crystals were colorless and transparent with maximum size o4 0.1 mm in diameter and 25 mm in length, The gas-sensing characteristics of Na+-doped anc undoped single crystals were investigated in 1 %H2. Co and CH, in air between 1 50 and 600℃. It was found that the undoped ZnO single crystals showed little gas sensitivity in air. and Na+-doping can greatly enhance the senstivity by increasing the resistivities. The maximum sensitivity of the samples is 22 (Ra/ Rg) for H2. 1 2 for CO and 4 for CH4

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Practice for Extending Blast Furnace Campaign Life at Wuhan Iron and Steel Corporation

ZHANG Shourong

钢铁研究学报(英文版)

One of the problems encountered in 60′s to 80′s of 20th century in China′s steel industry was short life of blast furnace shaft as well as the excessive erosion of blast furnace hearth. A series of research work was carried out in order to extend blast furnace campaign life. The concept of research and development was integrated in the construction of BF (blast furnace) No5 at WISCO (Wuhan Iron and Steel Corporation), and in October, 1991, the BF No5 was blown in. The blast furnace has worked smoothly for more than 15 years without any medium repair even guniting. It is expected that the campaign life of BF No5 would be longer than 16 years with a production over 11 000 t per unit inner volume (m3). A new blast furnace with an inner volume of 3 400 m3 is under construction, and is designed with a campaign life of 20 years without any medium repair. The campaign life of blast furnaces in China has been extended in recent years.

关键词: blast furnace;campaign life;erosion

Treatment of Reused Comprehensive Wastewater in Iron and Steel Industry With Electrosorption Technology

ZHANG Yunhua , GAN Fuxing , LI Meng , WANG Dihua , HUANG Zhongmai , GAO Yunpeng

钢铁研究学报(英文版)

Electrosorption technology was used to treat the reused comprehensive wastewater from iron and steel industry. A problem of relatively high conductivity of wastewater which greatly affects the reuse was examined, and industrial test was conducted for the reused water advanced deionization and purification in a comprehensive wastewater treatment plant of WISCO [Wuhan Iron and Steel (Group) Corporation]. The results of the onsite industrial test showed a satisfactory treatment performance for the reused water even at a flow rate of 1000 L/h in a standard 500 L/h unit. The average conductivity decreased by about 70%, from 580-780 μS/cm to 100-350 μS/cm. The average removal efficiency of Cl- and Ca2+ was about 75% and 68%, respectively, and CODCr of the treated water was also reduced in some degree while the pH value was almost unchanged. The energy consumption was as low as 06 kWh/t, which was remarkably superior to the conventional technologies. Therefore, it is entirely feasible that the novel electrosorption technology can be used in enhanced desalination and purification treatment of reused comprehensive wastewater in iron and steel industry.

关键词: electrosorption , desalination , purification , conductivity , industrial reused water

Titanium technology in the USA - an overview

D.Eylon , S.R.Seagle

材料科学技术(英)

The state of Ti research, development and industry is reviewed in this article. The fifty-year anniversary of Ti technology commercialization in the USA provides an opportunity for a historical perspective. Incorporation of "information-age" tools into alloy development, processing, and production invigorates the technology. Consolidation, diversification and globalization have been transforming the Ti industry in the recent years.

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